The kinetics of hydroisomerization of five hexane isomers over Pd/H-Mordenite catalyst has been studied at a temperature range 210-260℃, total pressure of 1.96MPa and H~2/hexane mole ratio of 8 in a combination unit of catalytic pressure microreactor and gas chromatograph. The results show that this complex reaction system could be assumed to be preudomonomolecular in the case of constant total pressure and constant H~2/hexane ratio. All the kinetic parameters of this reaction network have been calculated and the reaction activity energies are between 88.2-228kJ/mol.

Key words: DYNAMICS, HEXANE, NETBAGS, MORDENITE, ISOMERIZATION, COMPLEX REACTION