New synthetic methodology of five-membered cyclic compounds mediated by  zirconacycles

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (12): 2035-2041. Next Articles

Original Articles

锆诱导的五元环化合物的新和成

席婵娟;TAKAHASHI Tamotsu

清华大学化学系生命有机磷化学教育部重点实验室;北海道大学触媒化学研究中心.

发布日期:2001-12-15

New synthetic methodology of five-membered cyclic compounds mediated by zirconacycles

Xi Chanjuan;TAKAHASHI Tamotsu

Hokkaido Univ.

Published:2001-12-15

Abstract

This article describes four methodologies for the formation of five- membered carbocycles from zirconacycles. (1) Insertion reaction of CO or RNC to zirconacycles; (2) Reaction of zirconacycles with propynoate-combination of double Michael addition; (3) Reation of zirconacycles with iodopropenoates or iodocycloenones-combination of coupling reaction and Mechael addition; (4) Reaction of zirconacycles with acyl chlorides-combination of nucleophilic substitution and nuleophilic addition. Each of them has shown numeral representatives.

Key words: ZIRCONIUM, INDUCTION, FIVE MEMBER RING HETEROCYCLIC COMPOUNDS, REACTION MECHANISM, CARBON MONOXIDE, ADDITION REACTION

CLC Number:

O627

Cite this article

Xi Chanjuan;TAKAHASHI Tamotsu. New synthetic methodology of five-membered cyclic compounds mediated by zirconacycles[J]. Acta Chimica Sinica, 2001, 59(12): 2035-2041.

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锆诱导的五元环化合物的新和成

New synthetic methodology of five-membered cyclic compounds mediated by zirconacycles

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