Acta Chimica Sinica ›› 1995, Vol. 53 ›› Issue (10): 992-999. Previous Articles     Next Articles

Original Articles

含有十二烷基酚聚氧乙烯(10)醚的溶致液晶体系的研究

李干佐;翟利民;任学贞;郝树萱;隋华   

  1. 山东大学化学学院;山东大学实验中心
  • 发布日期:1995-10-15

Study of lyotropic liquid crystals containing nonionic surfactant of TX-10

LI GANZUO;DI LIMIN;REN XUEZHEN;HAO SHUXUAN;SUI HUA   

  • Published:1995-10-15

Lyotroic liquid crystals from nonionic surfactant (TX-10), styrene, and water were studied at 30℃ to determine the phase regions and obtain some typical photographs by using microscope with polarized-light. And the geometrical dimensions were determined by low angle X-ray diffractrion. The X-ray data showed that the structure of mesophase disclosed lamellar liquid crystals with Bragg spacing ratio of 1:1/2:1/3... For these lamellar liquid crystals the results indicated a linear increase of the interlayer spacing with addition of water or styrene and pronounced decrease with addition of TX-10 in the system. The ^2H NMR methods were specially applied to determine the exact liquid crystals' structure. It was found that the structure varied from mixed W/O type microemulsions and lamellar liquid crystals to single lamellar liquid crystals to single hexagonal liquid crystals to hexagonal liquid crystals and O/W type microemulsions in the liquid crystal region with the addition of the water. These results were discussed theoretically.

Key words: WATER, STYRENE, TERNARY SYSTEM, PHASE DIAGRAM, 2D NMR SPECTROMETRY

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