Acta Chimica Sinica ›› 2003, Vol. 61 ›› Issue (8): 1208-1212. Previous Articles     Next Articles

Original Articles

Mg-Al-NO_3层状双金属氢氧化物电性质研究

金志林;侯万国;张春光;孙祉伟   

  1. 山东大学;中国科学院力学研究所
  • 发布日期:2003-08-15

Studies on Electric Property of Mg-Al-Nitrate Layered Double Hydroxide

Jin Zhilin;Hou Wanguo;Zhang Chunguang;Sun Zhiwei   

  1. Key Laboratory for Colloid & Interface Chemistry of Education Ministry, Shangdong University;National Microgravity Laboratory, Institute of Mechanics, Chinese Academy of Science
  • Published:2003-08-15

Electrochemical parameters of Mg-Al-NO3LDH particles in different electrolytic solutions (LiCl, NaCl and KC1), including zeta potential, isoelectric point (Ph_(IEP)), permanent charge density (σ_P), and zero point of charge (pH_(ZPC)) have been measured by electrophoresis method and potentiometric titration. Effects of electrolyte, pH, and chemical composition on electric property of the positive sol were investigated. It has been found that the Ph_(IEP) decreases with the sequence of Li+, Na+, K+. Because of the permanent positive charge, the pH_(IEP) is not equal to the Ph_(ZPC); The values of bothσ_P and Ph_(ZPC) of Mg-Al-NO3IDH increase with the increase of the contents of Al3+ in the LDH samples, whereas the corresponding pHjEp decreases rather than the increase.

Key words: ELECTROLYTE, LITHIUM CHLORIDE, SODIUM CHLORIDE, POTASSIUM CHLORIDE, MAGNESIUM HYDROXIDE, ALUMINIUM HYDROXIDE, ELECTRIC POTENTIAL, ISOELECTRIC POINT, ELECTRICAL PROPERTIES

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