Acta Chimica Sinica ›› 1997, Vol. 55 ›› Issue (3): 229-235. Previous Articles     Next Articles

Original Articles

小角X衍射和ESR方法研究十二烷基磺酸钠/正戊醇/水三元体系的相结构

李方;李干佐;杨博;汪汉卿   

  1. 山东大学胶体与界面化学研究所;中国科学院兰州化学物理研究所
  • 发布日期:1997-03-15

Studies on the phase structure of As/n-C5H11OH/H2O systems with small angle X-ray diffraction and ESR methods

LI FANG;LI GANZUO;YANG BO;WANG HANQING   

  • Published:1997-03-15

The isothermal phase diagram for the system of sodium dodecyl sulfonate (As)/n-C5H11OH/H2O has been determined at 30℃. With small angle X-rfay diffraction, we investigated the liquid crystal area in the phase diagram. The results showed that all the liquid crystal is lamellar at certain temperature. Layer distance of liquid crystal increases with the increasing of water content and decreases with the increasing of n-C5H11OH content. The water permeability value not only depends on the water content, but also is affected by the alcohol content. The ESR studies showed that the structure parameter of the probe in the liquid crystal region is 0.32±0.02. The anisotropic degree of the probe rotating motion in the W/O and O/W micelle region increases with the increasing of water and oil content, respectively.

Key words: WATER, TERNARY SYSTEM, LIQUID CRYSTAL, ELECTRON SPIN RESONANCE, PENTANOL, PHASE DIAGRAM

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