Nickel chloride catalyzed reaction of allylic acetates with O,O-dialkyl phosphates

Acta Chimica Sinica ›› 1987, Vol. 45 ›› Issue (3): 312-313. Previous Articles Next Articles

Original Articles

无水二氧化镍催化下醋酸烯丙酯与亚膦酸二酯的反应

陆熙炎;朱景仰

中国科学院上海有机化学研究所

发布日期:1987-03-15

Nickel chloride catalyzed reaction of allylic acetates with O,O-dialkyl phosphates

LU XIYAN;ZHU JINGYANG

Published:1987-03-15

Abstract

Stirring H2C:CRCH2R1 (R = H, Me; R1 = OAc, CF3CO2) with R2R3P(O)H (R2 = EtO, BuO, Me2CHO, Ph; R3 = EtO, BuO, Me2CHO) at 100?in the presence of O,N-bis(trimethylsilyl) acetamide and NiCl2 gave 55-95% H2C:CRCH2P(O)R2R3.

Key words: ACETIC ACID ESTER, CATALYSIS, REACTION MECHANISM, REARRANGEMENT REACTION, ALLYL GROUP, NICKEL CHLORIDE, PHOSPHOROUS ACID ESTERS

CLC Number:

O627

Cite this article

LU XIYAN;ZHU JINGYANG. Nickel chloride catalyzed reaction of allylic acetates with O,O-dialkyl phosphates[J]. Acta Chimica Sinica, 1987, 45(3): 312-313.

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无水二氧化镍催化下醋酸烯丙酯与亚膦酸二酯的反应

Nickel chloride catalyzed reaction of allylic acetates with O,O-dialkyl phosphates

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