Acta Chimica Sinica ›› 2000, Vol. 58 ›› Issue (12): 1660-1665. Previous Articles     Next Articles

Original Articles

纳米二氧化硅复合悬浮液合成及聚合物吸附研究

华峰君;孙静;高濂;杨玉良   

  1. 复旦大学高分子科学系.上海(200433);复旦大学聚合物分子工程教育部重点实 验室;中国科学院上海硅酸盐研究所.上海(200050);中国科学院高性能陶瓷与超 微结构国家重点实验室
  • 发布日期:2000-12-15

Synthesis of TiO~2-SiO~2 nano-hybrid and its adsorption of polyelectrolyte

Hua Fengjun;Sun Jing;Gao Lian;Yang Yuliang   

  1. Fudan University, Department of Macromolecular Science.Shanghai (200433);Shanghai Inst Ceram., CAS.Shanghai(200050)
  • Published:2000-12-15

In this work, a nano-sized TiO~2-SiO~2 suspension solution was prepared by the precipitation of TiO~2 on silica particles of silica sol. The contribution of polymerically dispersed agent to the stability of suspension was investigated in detail. It was found that the dispersed agent of polyoxypropylene amine adsorbed on silica particles protected the agglomeration and stabilize silica sol. The hydrolysis of titanic ester-butanol-sulphuric acid is a reversible reaction in the origin silica sol, which decreased the controlling crystallinity of TiO~2, resulting in the precipitation of TiO~2 on origin silica particle. In the process of precipitation, the polyamine underwent ionic reaction in the tacidic conditions to form cationic circumstance annulus surrounding the complex nanoparticle. This double electrical lays reduced the aggregation or agglomeration and the core-shell complex nano balls composed of TiO~2-SiO~2 were synthesized.

Key words: SILICON DIOXIDE, NANOPHASE MATERIALS, HIGHPOLYMER, ADSORPTION, TITANIUM DIOXIDE, POLYETHERAMINE

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