Diastereoselective oxidation reaction between pyridinium chlorochromate and  tertiary α-hydroxy epoxides

Acta Chimica Sinica ›› 2001, Vol. 59 ›› Issue (12): 2191-2196. Previous Articles Next Articles

Original Articles

三级环氧醇与PCC的非对映性氧化反应研究

任世阔;樊春安;王保民;窦花妮;王飞;涂永强

兰州大学化学系.兰州(730000);兰州大学应用有机化学国家重点实验室.兰州 (730000)

发布日期:2001-12-15

Diastereoselective oxidation reaction between pyridinium chlorochromate and tertiary α-hydroxy epoxides

Ren Shikuo;Fan Chunan;Wang Baomin;Dou Huani;Wang Fei;Tu Yongqiang

Lanzhou Univ, Dept Chem.Lanzhou(730000);Lanzhou Univ, State Key Lab Appl Organ Chem.Lanzhou(730000)

Published:2001-12-15

Abstract

A novel diastereoselective oxidation reaction between pyridinium chlorochromate and the tertiary α-hydroxy epoxides is described. The stereoselectivity, chemoselectivity and the possible reaction mechanism have been discussed. This reaction could be developed to a synthetic method of chiral tertiary α-hydroxy epoxides as well as 1, 3-diones with a quaternary carbon at 2-position.

Key words: PYRIDINE P, CHROMIC ACID P, OXIDATION, KETONE, SELECTIVITY

CLC Number:

O621

Cite this article

Ren Shikuo;Fan Chunan;Wang Baomin;Dou Huani;Wang Fei;Tu Yongqiang. Diastereoselective oxidation reaction between pyridinium chlorochromate and tertiary α-hydroxy epoxides[J]. Acta Chimica Sinica, 2001, 59(12): 2191-2196.

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三级环氧醇与PCC的非对映性氧化反应研究

Diastereoselective oxidation reaction between pyridinium chlorochromate and tertiary α-hydroxy epoxides

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