Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (12): 1153-1158. Previous Articles     Next Articles

Original Articles

镍系胶体催化丁二烯聚合反应的研究Ⅰ: 催化剂的相态

夏少武;魏庆莉;左银雪;张书圣   

  1. 青岛化工学院应用化学系.青岛(266042)
  • 发布日期:1998-12-15

Studies on the polymerization of butadiene catalyzed by colloidal nickel systemⅠ: The phase state of catalyst

Xia Shaowu;Wei Qingli;Zuo Yinxue;Zhang Shusheng   

  1. Qindao Inst Chem Technol, Dept Appl Chem.Qingdao(266042)
  • Published:1998-12-15

The phase state of the catalytic system of Ni(naph)~2-Al(i-Bu)~3- (BF~3·OEt~2+n-C~8H~1~7OH) was studied. By means of Tyndall effect, electron microscope and ultrafiltration, we found that the catalyst dispersed in butadiene-hydrogasoline solution existed as colloidal particle and the particle sizes was from 1nm to 100nm. The catalyst belonged to highly dispersed polyphase catalytic system. The active center lay on the surface of the colloidal particles. The particles were amorphous. The ratio of components affected the shape of the particles. Under the better ratio we got smaller particles which were dispersed more uniformly and had higher catalytic activity.

Key words: COLLOID, CATALYST, NICKEL COMPLEX, ALUMINIUM COMPLEX, MULTICOMPONENT SYSTEM, PHASE STATE, ACTIVE CENTER, ELECTRON-MICROSCOPIC ANALYSIS

CLC Number: