Acta Chimica Sinica ›› 1998, Vol. 56 ›› Issue (12): 1159-1164. Previous Articles     Next Articles

Original Articles

镍系胶体催化丁二烯聚合反应的研究Ⅱ: 催化剂组分的 电导率和紫外光谱

夏少武;魏庆莉;李宁;张书圣   

  1. 青岛化工学院应用化学系.青岛(266042)
  • 发布日期:1998-12-15

Studies on the polymerization of butadiene catalyzed by colloidal nickel systemⅡ: The electric conductivity and UV-Vis spectrum of the catalyst

Xia Shaowu;Wei Qingli;Li Ning;Zhang Shusheng   

  1. Qindao Inst Chem Technol, Dept Appl Chem.Qingdao(266042)
  • Published:1998-12-15

Using electric conductivity and UV-Vis spectroscopy, the interaction between the catalyst components was further analyzed. The conclusions as follows were further verified: the catalyst components reacted with each other in the form of ionic pair. There existed Ni(0)-atom cluster (Ni^0)~m in aged solution of (Ni)-(Al). The cluster was very stable because of absorption of Ninaph and became bigger to form colloidal particles while adding (B). The active centers were located on the surface of colloidal particles. Butadiene didn't take part in the formation of active centers.

Key words: COLLOID, CATALYST, NICKEL COMPLEX, ALUMINIUM COMPLEX, MULTICOMPONENT SYSTEM, ELECTRICAL CONDUCTIVITY, ULTRAVIOLET SPECTROPHOTOMETRY, MICELLAE (=MICELLE), ACTIVE CENTER

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