Study of Adsorbed Ru(bpy)32+ on Glassy Carbon Electrode and Its Electrochemiluminescence

Acta Chimica Sinica ›› 2006, Vol. 64 ›› Issue (4): 320-324. Previous Articles Next Articles

Original Articles

玻碳电极上Ru(bpy)₃²⁺的吸附及其电致化学发光的研究

赵丽¹，陶颖¹，陈曦*^,1,2

(¹厦门大学化学化工学院化学系现代分析科学教育部重点实验室厦门 361005)
(²厦门大学近海海洋环境科学国家重点实验室厦门 361005)

投稿日期:2005-05-21 修回日期:2005-10-20 发布日期:2006-02-28
通讯作者: 陈曦

Study of Adsorbed Ru(bpy)₃²⁺ on Glassy Carbon Electrode and Its Electrochemiluminescence

ZHAO Li¹, TAO Ying¹, CHEN Xi*^,1,2

(¹ Department of Chemistry and the Key Laboratory of Analytical Sciences of the Ministry of Education,
College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005)
(² State Key Laboratory of Marine Environmental Science, Xiamen University, Xiamen 361005)

Received:2005-05-21 Revised:2005-10-20 Published:2006-02-28
Contact: CHEN Xi

Abstract

The adsorption of Ru(bpy)₃²⁺ on a glass carbon electrode has been investigated by cyclic voltammetry (CV) and electrochemiluminescence (ECL). Experimental results show that the adsorption of Ru(bpy)₃²⁺ on the surface of glass carbon electrode was obviously affected by the concentration of Ru(bpy)₃²⁺ and immersion time. The luminescent intensity decreases in the repetitive CV scan caused by the divorce of the oxidation product, , which made a great intensity change in the initiatory of ECL measurement.

Key words: electrochemiluminescence, Ru(bpy)₃²⁺, glass carbon electrode, adsorption

Cite this article

ZHAO Li, TAO Ying, CHEN Xi*^,1,2. Study of Adsorbed Ru(bpy)₃²⁺ on Glassy Carbon Electrode and Its Electrochemiluminescence[J]. Acta Chimica Sinica, 2006, 64(4): 320-324.

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玻碳电极上Ru(bpy)₃²⁺的吸附及其电致化学发光的研究

Study of Adsorbed Ru(bpy)₃²⁺ on Glassy Carbon Electrode and Its Electrochemiluminescence

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玻碳电极上Ru(bpy)32+的吸附及其电致化学发光的研究