A Heterojunction Based on Well-ordered Organic-Inorganic Hybrid Perovskite and Its Photovoltaic Performance

Acta Chimica Sinica ›› 2011, Vol. 69 ›› Issue (06): 627-632. Previous Articles Next Articles

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基于有机/无机杂化钙钛矿有序结构的异质结及其光伏性能的研究

杨志胜¹，杨立功*^{,1,2，吴刚¹，汪茫¹，陈红征*^,1,2}

(¹硅材料国家重点实验室高分子合成与功能构造教育部重点实验室
浙江大学高分子科学与工程学系杭州 310027)
(²浙江大学浙江加州国际纳米技术研究院杭州 310027)

投稿日期:2010-05-05 修回日期:2010-08-09 发布日期:2010-08-23
通讯作者: 杨志胜 E-mail:ydfyzs@yahoo.com.cn
基金资助:
国家自然科学基金项目;宽光谱、高迁移率的有机太阳能电池敏化染料;宽光谱、高迁移率的有机太阳能电池敏化染料

A Heterojunction Based on Well-ordered Organic-Inorganic Hybrid Perovskite and Its Photovoltaic Performance

Yang Zhisheng¹ Yang Ligong*^{,1,2 Wu Gang¹ Wang Mang¹ Chen Hongzheng*^,1,2}

(¹State Key Laboratary of Silicon Materials, MOE Key Laboratory of Macromolecule Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027)
(²Zhejiang-California International NanoSystems Institute, Zhejiang University, Hangzhou 310027)

Received:2010-05-05 Revised:2010-08-09 Published:2010-08-23
Contact: Zhi-Sheng YANG E-mail:ydfyzs@yahoo.com.cn

Abstract

Aggregation morphology and microscopic ordered characteristics of a novel organic-inorganic hybrid material (3-BrC₃H₆NH₃)₂CuBr₄ thin-film with perovskite structure were studied. Hall mobility test showed that the perovskite was p-type semiconductor with a hole mobility of 0.0025 cm²•V^－1•s^－1. The perovskite had good spectral response in the UV-Vis range with good complementarity with C₆₀. Planar heterojunctions consisting of (3-BrC₃H₆NH₃)₂CuBr₄/C₆₀ were fabricated to study the charge transport and photovoltaic performance. The effects of annealing temperature and aggregation morphology of the films on the performance of the photovoltaic prototype were also investigated. The results showed that the best performance of the devices was obtained after the low temperature annealing treatment, which led to an ordered organic array in the perovskite.

Key words: perovskite, organic-inorganic heterojunction, annealing temperature, photovoltaic performance

Cite this article

YANG Zhi-Sheng, YANG Li-Gong, WU Gang, WANG Mang, CHEN Hong-Zheng. A Heterojunction Based on Well-ordered Organic-Inorganic Hybrid Perovskite and Its Photovoltaic Performance[J]. Acta Chimica Sinica, 2011, 69(06): 627-632.

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基于有机/无机杂化钙钛矿有序结构的异质结及其光伏性能的研究

A Heterojunction Based on Well-ordered Organic-Inorganic Hybrid Perovskite and Its Photovoltaic Performance

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