Acta Chimica Sinica ›› 2012, Vol. 70 ›› Issue (06): 683-690.DOI: 10.6023/A1110081     Next Articles

Special Topic

邻甲酚在类水滑石、焙烧及改性类水滑石上的吸附

李燕, 施利文, 刘志山, 杨国庆   

  1. 长治学院化学系 长治 046011
  • 投稿日期:2011-10-08 修回日期:2012-01-10 发布日期:2012-01-20
  • 通讯作者: 李燕
  • 基金资助:

    国家自然科学基金(No. 20573065)、山西省高校科技开发(No. 20091038)和2010 年山西省普通高等本科学校大学生创新性实验资助项目.

Sorption of o-Cresol on Pristine, Calcined and Modified Hydrotalcite-like Compounds

Li Yan, Shi Liwen, Liu Zhishan, Yang Guoqing   

  1. Department of Chemistry, Changzhi College, Changzhi 046011
  • Received:2011-10-08 Revised:2012-01-10 Published:2012-01-20
  • Supported by:

    Project supported by the National Natural Science Foundation of China (No. 20573065), the project of Shanxi Province Higher Educational Science and Technology Program (No. 20091038) and 2010 Shanxi Province College of Innovative Pilot Project.

Mg-Al hydrotalcite-like compound (HTlc), calcined HTlc (CHTlc) and dodecylsulfate anionintercalated Mg-Al HTlc (DS·HTlc) were prepared. The sorption behavior of o-cresol on the HTlc, CHTlc and DS·HTlc was investigated. The sorption kinetics and sorption isotherms of o-cresol on the HTlc, CHTlc and DS·HTlc can all be well fitted with the pseudo-second order kinetic and Freundlich equation, respectively. The results indicated that the sorption rate and sorption amount of o-cresol on the DS·HTlc is much higher than that on the CHTlc, which is little higher than that on the HTlc. The sorption amount of o-cresol on the HTlc and CHTlc increased firstly and then decreased with increasing pH in the initial pH range of 5.00~13.00 and increased with increasing temperature. The sorption amount of o-cresol on the DS·HTlc decreased gradually with increasing initial pH and temperature. The sorption amount of o-cresol on the HTlc, CHTlc and DS·HTlc increased with the increasing electrolyte (NaCl) concentration. The sorption mechanism was discussed in detail and the DS·HTlc will be a new kind of highly effective adsorbent for phenolic pollution.

Key words: Mg-Al hydrotalcite-like compound (HTlc), calcined HTlc, dodecylsulfate ion-intercalated HTlc, o-cresol, sorption