Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions

doi:10.6023/A20050164

Acta Chimica Sinica ›› 2020, Vol. 78 ›› Issue (8): 713-718.DOI: 10.6023/A20050164 Previous Articles Next Articles

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新型共价交联纳米胶囊的构筑、调控与功能

闫腾飞^a, 刘俊秋^a,b

a 杭州师范大学材料与化学化工学院杭州 310036;
b 吉林大学化学学院超分子结构与材料国家重点实验室长春 130012

投稿日期:2020-05-12 发布日期:2020-05-30
通讯作者: 刘俊秋 E-mail:junqiuliu@jlu.edu.cn
作者简介:闫腾飞,1990年出生于河北石家庄,2019年博士毕业于吉林大学化学学院,高分子化学与物理专业,导师为刘俊秋教授.现为中南大学与杭州师范大学联合培养博士后,研究方向为生物超分子材料的制备与性能研究.
刘俊秋,吉林大学化学学院教授,1999年在吉林大学化学系高分子专业获理学博士学位.2002～2003年获洪堡基金资助在德国从事博士后研究.2003年加入吉林大学超分子结构与材料国家重点实验室,担任全职教授.2019年调入杭州师范大学材料与化学化工学院工作,研究方向包括仿生化学、蛋白质组装与功能化、生物材料.
基金资助:
项目受科技部重点研发项目基金（Nos.2018YF09101602，2018YFA0901600）资助.

Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions

Yan Tengfei^a, Liu Junqiu^a,b

a College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 310036;
b College of Chemistry, State Key Laboratory of Supramolecular Structure and Materials, Jilin University, Changchun 130012

Received:2020-05-12 Published:2020-05-30
Supported by:
Project supported by Key Research and Development Projects of the Ministry of Science and Technology (Nos. 2018YF09101602, 2018YFA0901600).

Monomolecular layer polymeric nanocapsules can be easily prepared by the covalent self-assembly of the horizontal cross-linking of rigid building blocks and flexible cross-linker under certain conditions. Compared with the traditional noncovalent supramolecular vesicles, this new type of covalently self-assembled polymeric nanocapsules possess many advantages such as stable structure, controllable size, and excellent dispersibility. Therefore, it is of great significance to fabricate new covalent nanocapsules by means of chemical synthesis to realize their structural control and application exploration. Focusing on these problems, we have developed functionalized pillar[5]arene, tetraphenyl ethylene, porphyrin, triazine, phenylboronic anhydride, etc. to serve as basic building blocks, which were polymerized by flexible alkyl linkers to finally obtain the covalently cross-linked polymeric nanocapsules. Through the structural modification and regulation, we found the functionalized polymeric nanocapsules showed potential application in the field of light harvesting, artificial enzyme, antimicrobial and drug delivery. In the future, more application fields of the covalent polymeric nanocapsules are expected to be further explored.

Key words: covalent cross-linking, monomolecular layer, nanocapsule, structural regulation, functionalization

Cite this article

Yan Tengfei, Liu Junqiu. Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions[J]. Acta Chimica Sinica, 2020, 78(8): 713-718.

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新型共价交联纳米胶囊的构筑、调控与功能

Novel Covalent Cross-linked Nanocapsules: Fabrication, Modulation and Functions

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