钯催化氧化/水解2-炔基芳基叠氮一锅法合成2-苯甲酰胺基苯甲酸

doi:10.6023/cjoc201909005

有机化学 ›› 2020, Vol. 40 ›› Issue (2): 462-469.DOI: 10.6023/cjoc201909005 上一篇下一篇

研究论文

钯催化氧化/水解2-炔基芳基叠氮一锅法合成2-苯甲酰胺基苯甲酸

圣戎, 李萍, 周志强, 胡贵文, 张小祥

南京林业大学化工学院江苏省生物质绿色燃料与化学品重点实验室南京 210037

收稿日期:2019-09-02 修回日期:2019-09-27 发布日期:2019-10-12
通讯作者: 张小祥 E-mail:zhangxiaoxiang@njfu.edu.cn
基金资助:
江苏省研究生创新计划（No.KYCX18_0967）、国家自然科学基金（No.21302096）、江苏省自然科学基金（No.BK20171449）、江苏高校“青蓝工程”资助项目.

Pd-Catalyzed One-Pot Oxidation/Hydrolysis for the Synthesis of 2-Benzoylaminobenzoic Acids from 2-Alkynyl Arylazides

Sheng Rong, Li Ping, Zhou Zhiqiang, Hu Guiwen, Zhang Xiaoxiang

College of Chemical Engineering, Jiangsu Key Laboratory of Biomass-based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing 210037

Received:2019-09-02 Revised:2019-09-27 Published:2019-10-12
Supported by:
Project supported by the Postgraduate Research & Practice Innovation Program of Jiangsu Province (No. KYCX18_0967), the National Natural Science Foundation of China (No. 21302096), the Natural Science Foundation of Jiangsu Province (No. BK20171449) and the Qing Lan Project.

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摘要/Abstract

描述了通过钯催化2-炔基芳基叠氮一锅法氧化/水解制备2-苯甲酰胺基苯甲酸的合成方法.在温和的反应条件下，反应以良好至极好的产率完成.

关键词: 钯催化, 一锅化反应, 氧化, 水解, 2-苯甲酰氨基苯甲酸

A synthetic method to prepare 2-benzoylaminobenzoic acids via Pd-catalyzed one-pot oxidation/hydrolysis from 2-alkynyl arylazides is described. The reaction was accomplished in good to excellent yields under mild reaction conditions.

Key words: Pd-catalyzed, one-pot reaction, oxidation, hydrolysis, 2-benzoylaminobenzoic acids

引用此文

圣戎, 李萍, 周志强, 胡贵文, 张小祥. 钯催化氧化/水解2-炔基芳基叠氮一锅法合成2-苯甲酰胺基苯甲酸[J]. 有机化学, 2020, 40(2): 462-469.

Sheng Rong, Li Ping, Zhou Zhiqiang, Hu Guiwen, Zhang Xiaoxiang. Pd-Catalyzed One-Pot Oxidation/Hydrolysis for the Synthesis of 2-Benzoylaminobenzoic Acids from 2-Alkynyl Arylazides[J]. Chinese Journal of Organic Chemistry, 2020, 40(2): 462-469.

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钯催化氧化/水解2-炔基芳基叠氮一锅法合成2-苯甲酰胺基苯甲酸

Pd-Catalyzed One-Pot Oxidation/Hydrolysis for the Synthesis of 2-Benzoylaminobenzoic Acids from 2-Alkynyl Arylazides

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