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有机化学
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有机化学 ›› 1983, Vol. 3 ›› Issue (4): 263-266. 上一篇    下一篇

研究论文

异核金属簇合成及催化作用的研究III.从铂(IV)合成铂(II)的络合物Pt[P(C6H5)3]Cl2*

翟纬绪;李达刚   

  1. 中国科学院兰州化学物理研究所
  • 发布日期:1983-08-25

Study on synthesis and catalysis of mixed-metal clusters iii. Synthesis of Pt(P(C6H5)3)2Cl2 from K2PtCl6

ZHAI WEIXU;LI DAGANG   

  • Published:1983-08-25

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关键词: 氧化, 氯络合物, 钾化合物, 有机过渡金属化合物, 铂络合物, 簇状化合物, 三苯基, 三苯基, 铂酸盐

This paper describes a new method of synthesizing platinum complex Pt(P(C6H5)3)2Cl2 from K2PtCl6 and P(C6H5)3 directly. The product have been identified by elemental analysis, physical constants determination, IR and mass spectra. By isolation and identification of the by-product (C6H5)3PO, it is shown that triphenylphosphine acts as the ligand and also the reducing agent in the reaction.

Key words: OXIDATION, CHLORO COMPLEX, POTASSIUM COMPOUNDS, ORGANO TRANSITION METAL COMPOUNDS, PLATINUM COMPLEX, CLUSTER COMPOUND, TRIPHENYL GROUP, TRIPHENYL GROUP, PLATINATE

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