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有机化学
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有机化学 ›› 1991, Vol. 11 ›› Issue (2): 214-218. 上一篇    下一篇

研究论文

6,7-(1',4'-亚丁基)-8-(4"-取代苯基)-10,10-二甲基-10H-吡啶并[1,2-α]吲哚盐的合成及波谱性质

宫勇;刘志杰   

  1. 西北大学化学系
  • 发布日期:1991-04-25

Syntheses and spectral properties of 6,7-(1',4'-butylene)-8 -(4"-substituted phenyl )-10,10-dimethyl-10H-pyrido [1,2-a]indolium perchlorates

GUONG YONG;LIU ZHIJIE   

  • Published:1991-04-25

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本文合成了6,7-(1',4'-亚丁基)-8-(4"-取代苯基)-10,10-二甲基-10H-吡啶并[1,2-α]吲哚盐,通过元素分析、IR 、^1HNMR、MS确定了化合物的结构,并对波谱性质及其它不同取代基常数之间的线性关系进行了讨论。

关键词: 吲哚 P, 质谱法, 质子磁共振谱法, 吲哚 P, 吡啶 P, 元素分析, 红外分光光度法, 苯 P, 环己酮 P, 烯烃

The title compounds (I; R = H, Me, Et, Cl, Br, OMe, OH, NMe2, NO2) were prepared by cyclocondensation of indolium salt II with benzylidenecyclohexanones III. The electronic absorption and fluorescence spectra, Stokes shifts, and some 1H NMR signals of I were measured, and linear relations with substituent constants were obtained.

Key words: INDOLE P, INDOLE P, PYRIDINE P, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, ELEMENTAL ANALYSIS, CYCLOHEXANONE P, INFRARED SPECTROPHOTOMETRY, BENZENE P, ALKENE

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