有机化学 ›› 1993, Vol. 13 ›› Issue (1): 79-83. 上一篇    下一篇

研究论文

仓库害虫集合信息素的合成锈赤扁谷盗和长角扁谷盗

孟岳;冯留贵;王树梅;滕有为   

  1. 中国科学院成都有机化学研究所
  • 发布日期:1993-02-25

Synthesis of the storage beetle aggregation pheromones cryptolestes ferrugineus and cryptolestes pusillus

MENG YUE;FENG LIUGUI;WANG SHUMEI;TENG YOUWEI   

  • Published:1993-02-25

本文报道通过不保护羟基的10-癸炔醇-1, 在LiNH2作用下直接与W-溴代羧酸酯反应引入羟酸基团, 从而缩补了反应步骤并提高了收率。十一碳烯内酯和十三碳烯内酯的心率为14.4%和11%, 立体选择性Z>98%。

关键词: 长角扁谷盗, 内酯, 信息素, 大环化合物, 耦合反应, 信息素, 炔烃 P, 锈赤扁谷盗

The monolefenic macrolide aggregation pheromone components 1 and 4 were synthesized through the alkylation and isomerization of alkyne. the 1, 4-dienemacrolide aggregation pheromone component 5 was synthesized through the couplinn reaction of alkynyl grignard reagent with p-methyl-bezessulfonate using the propargyl alcohol as starting material.

Key words: MACROCYCLIC COMPOUNDS, LACTONES, PHEROMONE, COUPLING REACTION, PHEROMONE, ALKYNE P

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