有机化学 ›› 1994, Vol. 14 ›› Issue (5): 545-548. 上一篇    下一篇

研究论文

通过烯丙基碲盐合成烯丙基硫醚的新方法

吕守茂;徐才丁;黄宪   

  1. 杭州大学化学系
  • 发布日期:1994-10-25

A new synthesis of allylthioethers via allyldialkyltelluronium salts

LU SHOUMAO;XU CAIDING;HUANG XIAN   

  • Published:1994-10-25

本文阐述了室温下,在NaOH存在下, 烯丙基二烃基溴化亚碲经苯硫酚或硫代烷基处理, 可高产率地得到烯丙基硫醚. 这一过程提供了一个有效的合成烯丙基硫醚的新方法.

关键词: 烯丙基化, 烯丙基硫醚 P, 烯丙基碲盐

Allyldialkyltelluronium bromides were treated with thiophenols or alkylthiols in the presence of NaOH at room temperature, readily giving allylthioethers in good yields. This procedure represents an efficient means for the synthesis of allylthioethers.

Key words: ALLYLATION

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