有机化学 ›› 1999, Vol. 19 ›› Issue (1): 97-103. 上一篇    

研究论文

电喷雾电离质谱在化学中应用新进展

魏先文;徐正   

  1. 南京大学配位化学研究所配位化学国家重点实验室
  • 发布日期:1999-02-25

A new progress of application of electrospary ionization mass spectrometry in chemistry

Wei Xianwen;Xu Zheng   

  • Published:1999-02-25

电喷雾电离质谱(ESI-MS)是本世纪发展的非常重要的质谱,具有无碎片的特点,可分析检测非挥发性的、极性的、热不稳定的化合物。评述了ESI-MS在富勒烯化学、无机配合物、簇合物、有机化学反应,金属有机化合物及超分子化学中的应用进展。

关键词: 应用, 电喷雾电离质谱, 簇合物, 质谱法, 富勒烯, 络合物

Electrospray ionization mass spectrometry (ESI-MS) is a very important mass spectrometry method developed in 20th century, with the characteristics of no fragmentation. The ESI-MS spectrometry has proven to be an extremely powerful technique for the analysis of involatile, polar and thermally labile compounds which exist as ions (positive and negative) in solution. This article reviewed the progress of application of ESI-MS to fullerene chemistry, inorganic complexes, clusters, organic reactions, organometallic compounds and supermolecular chemistry.

Key words: FULLERENES, MASS SPECTROGRAPHY, COMPLEX COMPOUNDS, APPLICATION

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