有机化学 ›› 2000, Vol. 20 ›› Issue (1): 22-29. 上一篇    下一篇

研究论文

过渡金属有机合物的取代反应

庞震;黄祖恩   

  1. 复旦大学化学系.上海(200433)
  • 发布日期:2000-02-25

Substitution reaction of transition organometallic compounds

Pang Zhen;Huang Zuen   

  1. Fudan Univ, Dept Chem.Shanghai(200433)
  • Published:2000-02-25

综述了有关金属有机合物取代反应的机理研究以及配体的电子效应,立体效应以及螯合效应等的因素对取代反应的影响。

关键词: 取代反应, 过渡金属化合物, 反应机理, 配体, 电子效应, 螯合作用, 立体效应

This article reviews the substitution reaction of organotransition metal compounds. The reaction methanism is affected by the electronic density on the metal and its ligands, the stereochemical environment around the metal centre and the chelation effect of its ligands.

Key words: SUBSTITUTION REACTION, TRANSITION METAL COMPOUND, REACTION MECHANISM, LIGANDS, ELECTRONIC EFFECT, CHELATION

中图分类号: