有机化学 ›› 2000, Vol. 20 ›› Issue (3): 282-292. 上一篇    下一篇

研究论文

天然产物合成中八元碳环的构建

李正邦;王锋鹏;陈东林   

  1. 华西医科大学药学院天然药化教研室
  • 发布日期:2000-06-25

Approaches to eight-membered carbocyclic rings in the synthesis of natural products

Li Zhengbang;Wang Fengpeng;Chen Donglin   

  • Published:2000-06-25

总结归纳了近年来天然产物合成中八元碳环构建的主要方法:环合反应、裂解反应以及涉及环扩张/收缩的重排反应。

关键词: 天然产物, 八元碳环, 构建, 环合反应, 裂解反应, 重排反应, 八碳化合物

This review provides a systematic summing-up of the different synthetic approaches to eight-membered carbocyclic rings, classified by the type of key reactions in clouding the cyclizations, fragmentations and rearrangements with the ring expansions/contractions.

Key words: NATURAL PRODUCTS, CONSTRUCTION, CRACKING REACTION, REARRANGEMENT REACTION, C8 COMPOUNDS

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