有机化学 ›› 2003, Vol. 23 ›› Issue (11): 1177-1184. 上一篇    下一篇

研究论文

苯乙烯内酯类天然产物的全合成进展

张兴贤;李卫东   

  1. 兰州大学化学系
  • 发布日期:2003-11-25

Progress in the Total Synthesis of Styryllactone Natural Products

Zhang Xingxian;Li Weidong   

  1. National Laboratory of Applied Organic Chemistry, Department of Chemistry, Lanzhou University
  • Published:2003-11-25

结合本研究小组的相关课题工作,综述了苯乙烯内酯类天然产物全合成方法的 研究进展。主要包括以呋喃甲醇类化合物的氧化重排反应、烯烃复分解环化反应( RCM)和酸催化的酯化关环等作为关键反应的方法。

关键词: 苯乙烯 P, 呋喃 P, 甲醇, 氧化, 重排反应, 烯烃, 复分解, 酯化, 内酯

In connection with our own research work, the recent advances in the total synthesis of styryllactone natural products are reviewed, which include the synthetic approaches involving the oxidative rearrangement of furanocarbinols, olefin ring closing metathesis (RCM) reaction, and acid-catalyzed lactonization as the key steps.

Key words: STYRENE P;FURAN P;METHANOL;OXIDATION;REARRANGEMENT REACTION, ALKENE;DOUBLE DECOMPOSITION;ESTERIFICATION;LACTONES

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