有机化学 ›› 2003, Vol. 23 ›› Issue (11): 1291-1293. 上一篇    下一篇

研究论文

微波辐射下9-芳基-10-对甲苯基多氢吖啶衍生物的合成

王香善;史达清;王苏惠;屠树江   

  1. 徐州师范大学化学系
  • 发布日期:2003-11-25

Synthesis of 9-Aryl-10-(4-methylphenyl)polyhydroacridine under Microwave Irradiation

Wang Xiangshan;Shi Daqing;Wang Suhui;Tu Shujiang   

  1. Department of Chemistry, Xuzhou Normal University
  • Published:2003-11-25

芳醛、5,5-二甲基-1,3-环已二酮(达米酮)与对甲基苯胺在以乙二醇为溶剂 ,微波辐射下反应生成一素列新的3,3,6,6-四甲基-1,8-二氧代-9-芳基-10-对 甲基苯基-1,2,3,4,5,6,7,8,9,10-十氢吖啶,产物的结构通过单晶X射线 衍射分析确证。

关键词: 吖啶, 微波辐射, 环己二酮 P, 苯胺 P, 乙二醇, X射线衍射分析

A series of 3, 3, 6, 6-tetramethyl-l, 8-dioxo-9-aryl-10-(4- methylphenyl)-l,2,3,4,5,6,7,8,9, 10-decaliydroacridines (4) have been synthesized from aromatic aldehydes, 5,5-dimethyl-l, 3- cyclohexanedione (dimedone) and p-toluidine in ethyleneglycol under microwave irradiation. The structure of the product 4b was confirmed by X-ray analysis.

Key words: ACRIDINE;MICROWAVE RADIATION;CYCLOHEXANEDIONE P;ANILINE P, ETHANEDIOL;XRD

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