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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (04): 414-418. 上一篇    下一篇

研究论文

间苯二酚杯芳烃树枝醇类化合物的合成

戈云，颜朝国*   

  1. (扬州大学化学化工学院 扬州225002)
  • 收稿日期:2004-05-10 修回日期:2004-11-02 发布日期:2005-03-30
  • 通讯作者: 颜朝国

Synthesis of Novel Calix[4]resorcinarene Core Arborols

GE Yun,YAN Chao-Guo*   

  1. (College of Chemistry & Chemical Engineering, Yangzhou University, Yangzhou 225002)
  • Received:2004-05-10 Revised:2004-11-02 Published:2005-03-30
  • Contact: YAN Chao-Guo

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被引次数

18 | 3

用间苯二酚杯芳烃的氧代乙酸乙酯类衍生物1a～1b分别与三羟甲基甲胺和二乙醇胺在乙醇/甲苯中进行酰胺化反应, 合成了四种新型的间苯二酚杯芳烃树枝醇化合物2a～2d, 树枝醇2a～2d外缘的羟基用乙酸酐酯化, 得到全乙酰基衍生物3a～3d. 化合物结构都用1H NMR, IR和元素分析等方法进行了表征, 对树枝醇化合物的聚集状态进行了光学显微镜观察.

关键词: 杯芳烃, 电镜, 间苯二酚杯芳烃, 树枝形化合物, 树枝醇

Four novel calix[4]resorcinarene core arborols 2a～2d bearing sufficient hydroxyl groups to impart the desired water solubility were conveniently synthesized by the reaction of calix[4]resorcinarene esters 1a～1b with tris(hydroxymethyl)aminomethane and bis(2-hydroxyethyl)amine respectively. These highly hygroscopic white solids were refluxed in Ac2O to form the corresponding acyl derivatives 3a～3d. The aggregation of arborol 2c containing hydrocarbon (lipophilic) backbone and twenty-four surface hydroxyl groups was observed in aqueous solution by TEM.

Key words: dendrimer, arborol, electron microscope, calix[4]resorcinarene, calixarene