有机化学 ›› 2005, Vol. 25 ›› Issue (12): 1583-1586. 上一篇    下一篇

研究简报

-碱金属氟化物在超声辐射下于水中诱发的芳香醛还原偶联

李记太*,陈艳雪,蔺志平,李同双   

  1. (河北大学化学与环境科学学院 河北省分析科学技术重点实验室 保定 071002)
  • 收稿日期:2001-01-26 修回日期:2005-06-06 发布日期:2005-11-30
  • 通讯作者: 李记太

Aluminum/fluoride Salt-mediated Reductive Coupling of Aromatic Aldehydes in Aqueous Media under Ultrasound Irradiation

LI Ji-Tai*, CHEN Yan-Xue, LIN Zhi-Ping, LI Tong-Shuang   

  1. (Key Laboratory of Analytical Science and Technology of Hebei Province, College of Chemistry and Environ-mental Science, Hebei University, Baoding 071002)
  • Received:2001-01-26 Revised:2005-06-06 Published:2005-11-30
  • Contact: LI Ji-Tai

超声辐射下, 铝粉在氟化钾或氟化钠的水溶液中, 可使芳香醛快速还原或偶联, 生成相应的双分子还原偶联产物和少量单分子还原产物, 其中还原偶联产物邻二醇的收率达15%~82%.

关键词: 超声辐射, 还原偶联, 邻二醇, 合成

Under ultrasound irradiation, reductive coupling of aromatic aldehydes mediated by Al/KF or NaF in aqueous media afforded 1,2-diol in 15%~82% yields.

Key words: 1,2-diol, synthesis, reductive coupling, ultrasound irradiation