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有机化学
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有机化学 ›› 2005, Vol. 25 ›› Issue (9): 1049-1052. 上一篇    下一篇

研究论文

1,3-二噁烷环的双磺酸盐表面活性剂的微波合成

袁先友1,2，阳年发*,1，罗和安1，刘跃进1   

  1. (1湘潭大学化学化工学院 湘潭411105)
    (2湖南科技学院化学系 永州 425006)
  • 收稿日期:2004-10-25 修回日期:2005-03-18 发布日期:2005-08-24
  • 通讯作者: 阳年发

Microwave Syntheses of Disulfonate Salt-type Cleav-ableSurfactants with a 1,3-Dioxane Ring

YUAN Xian-You1,2,YANG Nian-Fa*,1,LUO He-An1,LIU Yue-Jin1   

  1. >(1 College of Chemistry and Engineering, Xiangtan University, Xiangtan 411105)
    (2 Department of Chemistry, Hunan University of Science and Engi-neering, Yongzhou 425006)
  • Received:2004-10-25 Revised:2005-03-18 Published:2005-08-24
  • Contact: YANG Nian-Fa

PDF

1644

被引次数

13

在微波辐射下, 以磷钨酸为催化剂, N,N-二甲基甲酰胺为溶剂, 将2,2-二羟甲基-1,3-丙二醇与醛缩合合成了单缩醛, 然后与氢化钠和1,3-丙磺内酯反应得到含1,3-二噁烷环的双磺酸盐表面活性剂. 产物经过元素分析、IR和1H NMR表征.

关键词: 2,2-二羟甲基-1,3-丙二醇, 缩醛, 1,3-二噁烷, 微波辐射, 双磺酸盐表面活性剂

A series of disulfonate salt-type cleavable surfactants with a 1,3-dioxane ring were synthesized by the condensation of aldehydes with 2,2-bis(hydroxymethyl)-1,3-propanediol using phosphotungstic acid as catalyst and dimethylformamide as solvent under microwave irradiation, followed by reaction with 1,3-propanesultone in the presence of sodium hydride, and characterized by elemental analysis, IR and 1H NMR spectra.

Key words: acetal, 2,2-bis(hydroxymethyl)-1,3-propanediol, 1,3-dioxane, microwave irradiation, disulfonate salt-type cleavable surfactant