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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (04): 556-558. 上一篇    下一篇

研究简报

固相熔融合成含4,4'-联吡啶二阳离子的哑铃型化合物

齐建永1，张青丽1，许新华*,1，黎小武1,2，贺干武1,2
王炳清1,3，卢锐亮1，方敬坤1   

  1. (1湖南大学化学化工学院 长沙 410082)
    (2邵阳学院化学系 邵阳 422400)
    (3新疆吐鲁番地区实验中学 吐鲁番 838000)
  • 收稿日期:2005-04-06 修回日期:2005-10-31 发布日期:2006-03-31
  • 通讯作者: 许新华*

Synthesis of Dumbbell-Shape Compound Contain-ing4,4'-Bipyridinium Dication under Solid Phase Fusion

QI Jian-Yong1,ZHANG Qing-Li1,XU Xin-Hua*,1,LI Xiao-Wu1,2,HE Gan-Wu1,2
WANG Bing-Qing1,3,LU Rui-Liang1,FANG Jing-Kun1   

  1. (1 College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082)
    (2 Department of Chemistry, Shaoyang University, Shaoyang 422400)
    (3 Tulufan District High School, Tulufan 838000)
  • Received:2005-04-06 Revised:2005-10-31 Published:2006-03-31
  • Contact: Xu Xin-Hua

PDF

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2-{2-[4-苯基-二(4-特丁基苯基)甲基]苯氧基}乙氧乙醇磺酸酯(2.1 mmol)与4,4'-联吡啶(1.0 mmol)混合, 加热到融化, 搅拌10 min, 用石油醚洗涤反应混合物, 得到定量的哑铃型化合物.

关键词: 无溶剂, 哑铃型化合物, 无催化剂, 固相融溶, 合成

The mixture of tosylate of 2-{2-{4-[1-phenyl-1,1'-bis(4-tert-butylphenyl)methyl]phenoxy}ethoxy}ethanol and 4,4'-bipyridine was heated to melt for 10 min, then washed with petroleum. The dumbbell-shape compound containing 4,4'-bipyridinium dication was yielded quantitatively.

Key words: uncatalyzed, dumbbell-shape compound, solid phase fusion, synthesis, solvent-free