有机化学 ›› 2007, Vol. 27 ›› Issue (01): 34-44. 上一篇    下一篇

综述与进展

金属卟啉配合物的催化氧化应用研究进展

李臻,景震强,夏春谷*   

  1. (中国科学院兰州化学物理研究所 羰基合成与选择氧化国家重点实验室 兰州 730000)
  • 收稿日期:2006-01-06 修回日期:1900-01-01 发布日期:2006-12-30
  • 通讯作者: 夏春谷

Review on Application of Metalloporphyrins in Catalytic Oxidation Reactions

LI Zhen,JING Zhen-Qiang,XIA Chun-Gu*   

  1. (State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics,
    Chinese Academy of Sciences, Lanzhou 730000)
  • Received:2006-01-06 Revised:1900-01-01 Published:2006-12-30
  • Contact: XIA Chun-Gu

综述了近年来金属卟啉作为催化剂在各种氧化反应中应用的研究进展, 着重介绍了均相体系和非均相体系中各种金属卟啉模拟酶的催化性能.

关键词: 催化氧化, 固载, 细胞色素P-450, 金属卟啉

Recent progress of application of metalloporphyrins in catalytic oxidation systems is reviewed. The focus is especially on their catalytic performance in homogenous and heterogenous reaction systems.

Key words: supported, metalloporphyrin, catalytic oxidation, cytochrome P-450