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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (01): 45-65. 上一篇    下一篇

综述与进展

C＝N双键的不对称烯丙基化反应

陶传洲，张威，刘磊，郭庆祥*   

  1. (中国科学技术大学化学系 合肥 230026)
  • 收稿日期:2005-08-11 修回日期:1900-01-01 发布日期:2006-12-30
  • 通讯作者: 郭庆祥

Asymmetric Allylation of C＝N Double Bonds

TAO Chuan-Zhou,ZHANG Wei,LIU Lei,GUO Qing-Xiang*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • Received:2005-08-11 Revised:1900-01-01 Published:2006-12-30
  • Contact: GUO Qing-Xiang

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1125

被引次数

1

详细地综述了有关C＝N双键立体选择性烯丙基化反应的研究进展. 重点讲述了使用手性辅助基团、手性试剂以及不对称催化剂进行C＝N双键不对称烯丙基化的方法.

关键词: C＝N双键, 烯丙基化反应, 不对称合成

This article thoroughly reviews the studies on the asymmetric allylation reactions of C＝N double bonds. The main focuses are the asymmetric allylation reactions of C＝N double bonds through using chiral auxiliary groups, chiral allylation reagents, and asymmetric catalysts.

Key words: allylation, asymmetric synthesis, C＝N double bond