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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (10): 1220-1227. 上一篇    下一篇

综述与进展

含四硫富瓦烯大环化合物的合成与研究进展

李洪启*,a，宋燕西b，彭家建c，邱化玉c   

  1. (a东华大学化学与化工学院 上海 201620)
    (b东华大学环境科学与工程学院 上海 201620)
    (c杭州师范学院有机硅化学及材料技术重点实验室 杭州 310012)
  • 收稿日期:2006-12-11 修回日期:2007-01-17 发布日期:2007-09-28
  • 通讯作者: 李洪启

Advances in Synthesis and Research of Macrocyclic Compounds Containing Tetrathiafulvalene

LI Hong-Qi*,a,SONG Yan-Xib,PENG Jia-Jianc,QIU Hua-Yuc   

  1. (a College of Chemistry and Chemical Engineering, Donghua University, Shanghai 201620)
    (b College of Environmental Science and Engineering, Donghua Univer-sity, Shanghai 201620)
    (c Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education,
    Hangzhou Teachers College, Hangzhou 310012)
  • Received:2006-12-11 Revised:2007-01-17 Published:2007-09-28
  • Contact: LI Hong-Qi

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1644

被引次数

30 | 6

简要介绍了含有四硫富瓦烯(TTF)单元的大环化合物的分类, 概括了各类含四硫富瓦烯大环化合物的合成方法, 主要包括含有1,3-二硫杂环戊烯-2-硫酮单元的大环化合物在亚磷酸三烷基酯参与下的偶合反应, 以及带有氰乙基硫等取代基的预先合成的官能化TTF与二卤代低聚醚的反应. 综述了含四硫富瓦烯大环化合物的电化学性能及其在分子识别方面应用研究的最新进展, 提出了含四硫富瓦烯大环化合物的发展趋势.

关键词: 分子识别, 四硫富瓦烯, 大环化合物, 电化学性能, 合成

Classification of macrocyclic compounds containing tetrathiafulvalene is introduced briefly. The synthetic methods of macrocyclic compounds containing tetrathiafulvalene are outlined, which mainly include the coupling reaction of a macrocyclic compound containing a 1,3-dithiole-2-thione unit mediated by trialkyl phosphite and reactions between a well-designed tetrathiafulvalene functionalized by cyanoethylthio groups or other substituents and an oligo (ethylene glycol) dihalide. The latest advances in research on electrochemical properties and applications to molecular recognition of macrocyclic compounds containing tetrathiafulvalene are reviewed. The development trends in research on such macrocyclic compounds containing tetrathiafulvalene are proposed.

Key words: macrocyclic compound, synthesis, electrochemical property, molecular recognition, tetrathiafulvalene