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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (10): 1195-1219. 上一篇    下一篇

综述与进展

基于肽的不对称催化剂

刘爱香，傅尧，刘磊，郭庆祥*   

  1. (中国科学技术大学化学系 合肥 230026)
  • 收稿日期:2006-10-19 修回日期:2007-02-02 发布日期:2007-09-28
  • 通讯作者: 郭庆祥

Peptide-Based Asymmetric Catalysts

LIU Ai-Xiang,FU Yao,LIU Lei, GUO Qing-Xiang*   

  1. (Department of Chemistry, University of Science and Technology of China, Hefei 230026)
  • Received:2006-10-19 Revised:2007-02-02 Published:2007-09-28
  • Contact: GUO Qing-Xiang

PDF

1149

被引次数

4 | 1

综述了肽作为有机催化剂以及金属配体在不对称催化反应中的应用, 概括了人们所发现的各种肽催化剂的结构、催化活性以及机理, 并对发现这些肽的过程中所采用的研究方法做了具体的介绍.

关键词: 肽, 有机催化剂, 组合化学, 配体

Peptide-based organocatalysts and peptide-ligated transition metal catalysts are reviewed in the context of asymmetric catalysis. The structures, activities, and mechanisms of these catalysts are described in detail. Furthermore, we also survey the methods that are developed to screen library of peptides in the search of active catalysts.

Key words: organocatalyst, ligand, combinatorial chemistry, peptide