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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (01): 104-110. 上一篇    下一篇

研究论文

手性胍盐离子液体的合成

吴楠，吴海虹，蒋咏文*   

  1. (华东师范大学化学系 上海市绿色化学与化工过程绿色化重点实验室 上海 200062)
  • 收稿日期:2007-02-01 修回日期:1900-01-01 发布日期:2008-01-23
  • 通讯作者: 蒋咏文

Synthesis of Chiral Guanidinium-Based Ionic Liquids

WU Nan, WU Hai-Hong, JIANG Yong-Wen*   

  1. (Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Deparment of Chemistry,
    East China Normal University, Shanghai 200062)
  • Received:2007-02-01 Revised:1900-01-01 Published:2008-01-23
  • Contact: JIANG Yong-Wen

PDF

956

被引次数

16

以1,3-二甲基-2-咪唑啉酮, α-甲基苄胺为原料, 三步合成了手性胍的氯盐, 再经复分解反应, 共合成了14种手性胍离子液体并对其结构性质进行了表征. 该类离子液体有望用于催化不对称Henry 反应、Michael加成反应等.

关键词: 1,3-二甲基-2-咪唑啉酮, (S)-1-甲基苄胺, 手性胍, 离子液体

Chiral guanidinium chloride salts were synthesized from 1,3-dimethyl-2-imidazolidinone and (S)-1-phenylethylamine. 14 ionic liquids with different anions were obtained by metathesis reactions of the chiral guanidinium chloride with MX and characterized by 1H NMR, 13C NMR, ESI-MS, and TGA methods. These guanidinium-based ionic liquids are potential catalysts to some reactions such as asymmetric Henry reaction or Michael addition.

Key words: (S)-1-phenylethylamine, 1,3-dimethyl-2-imidazolidinone, chiral guanidine, ionic liquid