有机化学 ›› 2008, Vol. 28 ›› Issue (2): 175-180.    下一篇

综述与进展

Baylis-Hillman反应机理研究进展

杨春红,樊建芬*,乔龙光   

  1. (苏州大学化学化工学院 苏州 215123)
  • 收稿日期:2006-12-25 修回日期:2007-04-20 发布日期:2008-02-01
  • 通讯作者: 樊建芬

Recent Advances in the Study of the Mechanism of Baylis-Hillman Reaction

YANG Chun-Hong,FAN Jian-Fen*,QIAO Long-Guang   

  1. (Faculty of Chemistry and Chemical Engineering, Suzhou University, Suzhou 215123)
  • Received:2006-12-25 Revised:2007-04-20 Published:2008-02-01
  • Contact: FAN Jian-Fen

介绍了一种形成碳—碳键的方法——Baylis-Hillman反应, 综述了单分子醛、双分子醛反应机理、TiCl4催化机理、不对称诱导机理以及低温效应、溶剂效应、离子液体反应机理的研究进展.

关键词: Baylis-Hillman反应, 反应机理, 综述

A C—C bond forming reaction, namely Baylis-Hillman reaction, is described and the recent progress is reviewed in the study of the reaction mechanisms of the single molecular aldehyde and the double molecular aldehyde, TiCl4 catalytic mechanism, asymmetric induction mechanism, temperature and sol-vent effects as well as the ionic liquid reaction mechanism.

Key words: mechanism, Baylis-Hillman reaction, review