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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (01): 34-43. 上一篇    下一篇

综述与进展

四硫富瓦烯及其衍生物在分子开关领域的研究进展

朱玉兰*,a,b ; 周鑫鑫a,b ; 尹起范a ; 曹 丽a   

  1. (a淮阴师范学院化学系 江苏省低维材料化学重点建设实验室 淮安 223300)
    (b延边大学理学院化学系 延吉 133002)
  • 收稿日期:2008-01-24 修回日期:2008-04-30 发布日期:2009-01-20
  • 通讯作者: 朱玉兰

Advance in Tetrathiafulvalene and Its Derivatives as Molecular Switches

Zhu, Yulan*,a,b; Zhou, Xinxin a,b; Yin, Qifana; Cao, Lia   

  1. (a Jiangsu Key Laboratory for Chemistry of Low-dimensional Materials, Department of Chemistry, Huaiyin Teacher’s College, Huai’an 223300)
    (b Department of Chemistry, College of Science, Yanbian University, Yanji 133002)

  • Received:2008-01-24 Revised:2008-04-30 Published:2009-01-20
  • Contact: Zhu, Yulan

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被引次数

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四硫富瓦烯(TTF)及其衍生物由于具有特殊的结构和性质, 在分子开关、分子传感器、光信息存储和非线性光学等领域显示出诱人的应用前景. 综述了近几年TTF及其衍生物在分子开关领域的最新研究进展.

关键词: 分子识别, 四硫富瓦烯, 合成, 分子开关

Tetrathiafulvalene (TTF) and its derivatives can be reversibly transformed into the radical cation TTF•+ and dication TTF2＋ through either chemical or electrochemical oxidation. By using of this feature, TTF and its derivatives have been widely investigated for their potential use in molecular switches, molecular sensors, optical information storage and nonlinear optics etc. This article reviews the recent progress in TTF and its derivatives as molecular switches such as fluorescence switch, photochromism switch, chiral switch and supramolecular switch.

Key words: synthesis, molecular switch, molecular recognition, tetrathiafulvalene