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有机化学
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有机化学 ›› 2010, Vol. 30 ›› Issue (08): 1126-1141. 上一篇    下一篇

综述与进展

手性溶解剂在NMR法测定对映体比率和绝对构型的研究进展

王文革1，申秀民2，张聪*,2   

  1. (1湖南工学院化工系 衡阳 421002)
    (2北京师范大学化学学院 北京 100875)
  • 收稿日期:2009-09-07 修回日期:2010-01-21 发布日期:2010-02-05
  • 通讯作者: 张聪 E-mail:czhang@bnu.edu.cn
  • 基金资助:

    国家级.国家自然科学基金

Progress on Application of NMR Chiral Solvating Agents to Deter-mine Enantiomeric Ratio and Absolute Configuration

Wang Wenge1 Shen Xiumin2 Zhang Cong*,2   

  1. (1 Department of Chemical Engineering, Hunan Institute of Technology, Hengyang 421002)
    (2 College of Chemistry, Beijing Normal University, Beijing 100875)
  • Received:2009-09-07 Revised:2010-01-21 Published:2010-02-05
  • Contact: ZHANG Cong E-mail:czhang@bnu.edu.cn

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被引次数

2

综述了手性溶解剂在NMR法测定对映体比率及绝对构型的研究进展. 按照手性溶解剂的结构类型, 包括胺、酰胺、羧酸、醇、氨基醇、大环化合物, 对手性溶解剂的结构特点与手性识别性能进行了详细的介绍.

关键词: 手性溶解剂, 对映体比率, 绝对构型, 进展

The progress on application of NMR chiral solvating agents to determine enantiomeric ratio and absolute configuration is reviewed. According to the structural style of chiral solvating agents, e.g. amines, amides, carboxylic acids, alcohols, amino alcohols and macrocyclic compounds, their structural style as well as chiral recognition is described in detail.

Key words: chiral solvating agent, enantiomeric ratio, absolute configuration, progress