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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (11): 1857-1863. 上一篇    下一篇

综述与进展

液晶二聚体

白炳莲a,b ; 于智莘a ; 王海涛a ; 李 敏*,a   

  1. (a汽车材料教育部重点实验室 吉林大学材料科学与工程学院 长春 130012)
    (b吉林大学物理学院 长春 130023)
  • 收稿日期:2007-12-26 修回日期:2008-03-07 发布日期:2008-11-18
  • 通讯作者: 李 敏

Liquid Crystal Dimers

BAI, Bing-Lian a,b; YU, Zhi-Xin a; WANG, Hai-Taoa; LI, Min*,a   

  1. (a Key Laboratory for Automobile Materials, Ministry of Education, Institute of Materials Science and Engineering,
    Jilin University, Changchun 130012)
    (b College of Physics, Jilin University, Changchun 130023)
  • Received:2007-12-26 Revised:2008-03-07 Published:2008-11-18
  • Contact: LI, Min

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被引次数

4

液晶二聚体作为半柔性主链型液晶聚合物的简化模型, 通过对其液晶性质的研究, 有助于理解更复杂聚合物体系的液晶行为. 另外, 液晶二聚体作为一类特殊的液晶也有其自身的相结构和相行为. 以分子结构与液晶态的相互关系为主线, 系统介绍了目前文献报道的对称及非对称棒状液晶二聚体(线形、H形、U形、T形)、盘状液晶二聚体(对称的盘-盘状液晶二聚体和非对称的盘-棒状液晶二聚体)和香蕉形液晶二聚体(对称的香蕉-香蕉形液晶二聚体和非对称的香蕉-棒状液晶二聚体)等各种不同类型的液晶二聚体的研究进展, 以期为新型液晶二聚体的分子设计提供一些借鉴.

关键词: 香蕉形, 氢键, 液晶二聚体

Liquid crystal dimers serve as useful model compounds for the semi-flexible main chain liquid crystal polymers. The mesophases of more complex polymeric systems can be comprehended through the study of the properties of liquid crystal dimers. In addition, the liquid crystal dimers are of significant interest in their own right. This paper presents a brief review on the structure-property relationships and the recent progress in different types of liquid crystal dimers: symmetric and non-symmetric calamitic liquid crystal dimers (linear shape, H shape, U shape and T shape), discotic liquid crystal dimers (symmetric discotic- discotic, non-symmetric discotic-calamitic liquid crystal dimers) and banana-shaped liquid crystal dimers (symmetric banana-banana shaped, non-symmetric calamitic-banana shaped liquid crystal dimers), which might be the guidance for designing novel liquid crystal dimers.

Key words: banana-shape, hydrogen bondi, liquid crystal dimer