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有机化学
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有机化学 ›› 2008, Vol. 28 ›› Issue (11): 1864-1874. 上一篇    下一篇

综述与进展

稳定烯醇及其合成方法学

胡乔舒 ; 席振峰*   

  1. (北京大学化学与分子工程学院 北京分子科学国家实验室 生物有机与分子工程教育部重点实验室 北京 100871)
  • 收稿日期:2008-12-23 修回日期:2008-04-01 发布日期:2008-11-18
  • 通讯作者: 席振峰

Stable Enols and Their Synthetic Methodologies

HU, Qiao-Shu; XI, Zhen-Feng*   

  1. (Beijing National Laboratory for Molecular Sciences, Key Laboratory of Bioorganic Chemistry and Molecular Engineering, Ministry of Education, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871)
  • Received:2008-12-23 Revised:2008-04-01 Published:2008-11-18
  • Contact: XI, Zhen-Feng

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2562

被引次数

4

烯醇受环境因素和取代基的影响在一定条件下可以稳定存在. 研究稳定烯醇的结构特点、反应性质在有机化学理论研究和有机合成化学中有重要意义. 从影响烯醇稳定的因素以及稳定烯醇合成方法学的角度对该领域进行了综述, 分别讨论了芳基取代烯醇和脂肪基取代烯醇的稳定性及其合成方法.

关键词: 烯醇, 稳定性, 合成, 互变异构

Enols can be stable or even isolable by bearing special substituents or in proper environments. The study of structures and chemical behavior of stable enols is important from both theoretical and synthetic points of view. Here, the stabilities and synthetic methodologies of aromatic and aliphatic enols are discussed.

Key words: enol, tautomerization, synthesis, stability