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有机化学
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有机化学 ›› 2001, Vol. 21 ›› Issue (12): 1132-1136. 上一篇    下一篇

研究论文

M2TNR(M=AG, CHZ)的制备和晶体结构

杨利;张同来;张建国;杨永明;冯长根;郁开北   

  1. 北京理工大学机电工程学院.北京(100081);中科院成都有机所分析测试中心
  • 发布日期:2001-12-25

Preparation and crystal structure of M2TNR(M=AG, CHZ)

Yang Li;Zhang Tonglai;Zhang Jianguo;Yang Yongming;Feng Changgen;Yu Kaibei   

  1. Beijing Univ. of polytechnol., North-China Univ of Electr Power. Beijing(100081)
  • Published:2001-12-25

PDF

548

被引次数

6

通过三硝基间苯二酚(TNR，斯蒂酚酸)和氨基胍(AG)重碳酸盐、碳酰肼(CHZ)反应，制备斯蒂酚酸氨基胍和斯蒂酚酸碳酰肼。并用X-射线衍射分析、元素分析、差示扫描量热法和红外光谱对其进行了结构表征。它们的分子式分别为(NH2NHCNHNHNH2)2^+[C6H(NO3)3O2]^2.0.5H2O,(NH2NHCONHNH3)2^+[C6H(NO3)3O2]^2^-，二者都属于单斜晶系，C2/c空间群。

关键词: 制备, 结构表征, 碳酰肼P, 氨基胍P, 三硝基苯酚P, 斯蒂酚酸, 晶体结构

M2TNR(M=AG, CHZ) was prepared by mixing styphnic acid and aminoguanidine bicarbonate or carbohydrazide. The products were characterized by X-ray diffraction analysis, element analysis, DSC, and IR measurement. The salts could be expressed in the formula of (NH2NHCNHNHNH2)2^+[C6H(NO3)3O2]^2.0.5H2O or (NH2NHCONHNH3)2^+[C6H(NO3) 3O2]^2^-. The crystals belong to monoclinic, space group C2/c.

Key words: PREPARATION, STRUCTURE CHARACTERISTICS, CARBOHYDRAZIDE P, AMINOGUANIDINE P, CRYSTAL STRUCTURE

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