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有机化学
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有机化学 ›› 2009, Vol. 29 ›› Issue (02): 197-205. 上一篇    下一篇

综述与进展

基于四硫富瓦烯衍生物Langmuir-Blodgett膜的研究进展

李洪启*; 宋燕西; 李秀梅   

  1. (a东华大学化学化工与生物工程学院 上海 201620)
    (b东华大学环境科学与工程学院 上海 201620)
    (c内蒙古通辽职业学院理工系 通辽 028000)
  • 收稿日期:2008-03-11 修回日期:2008-06-25 发布日期:2009-02-20
  • 通讯作者: 李洪启

Advances in Study on Langmuir-Blodgett Films Based on Tetrathiafulvalene Derivatives

Li, Hongqi* ; Song, Yanxi; Li, Xiumei   

  1. (a College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620)
    (b College of Environmental Science and Engineering, Donghua University, Shanghai 201620)
    (c Department of Physics and Technology, Inner Mongolia Tongliao Vocational College, Tongliao 028000)
  • Received:2008-03-11 Revised:2008-06-25 Published:2009-02-20
  • Contact: Li, Hongqi

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在简要介绍了Langmuir-Blodgett (LB)膜的基础上, 主要依据制备LB膜的四硫富瓦烯(TTF)衍生物化学结构的不同, 概括了基于两亲性TTF衍生物、非两亲性TTF衍生物、TTF电荷转移(CT)复合物或盐、以及TTF金属络合物LB膜的制备、结构表征与性能研究进展. 介绍了基于TTF衍生物的LB膜在导电、化学及生物传感器、光学以及磁性方面的应用, 并对基于TTF衍生物LB膜的发展进行了展望.

关键词: 光学, 磁性, 传感器, 四硫富瓦烯, Langmuir-Blodgett膜, 导电性

After a brief introduction to Langmuir-Blodgett (LB) film, advances in preparation, structural characterization and property study of LB films based on amphiphilic tetrathiafulvalene (TTF) derivatives, non-amphiphilic TTF derivatives, TTF CT complexes or salts, and TTF metal complexes are reviewed mainly according to different structures of the TTF derivatives. Applications of LB films based on the TTF derivatives to electrical conduction, chemical sensors or biosensors, optics, and magnetism are introduced. Moreover, the development trends in research on LB films based on the TTF derivatives are proposed.

Key words: Langmuir-Blodgett film, magnetism, sensor, conductivity, optics, tetrathiafulvalene