有机化学 ›› 1987, Vol. 7 ›› Issue (3): 189-192. 上一篇    下一篇

研究论文

水溶性meso-四咪唑基卟啉及其金属配合物的合成

黄枢;丁力;王先元;李广年   

  1. 四川大学化学系;中国科学院成都有机化学研究所
  • 发布日期:1987-06-25

Sntheses of water soluble meso-tetraimidazolyl porphyrines and their metal complexes

HUANG SHU;DING LI;WANG XIANYUAN;LI GUANGNIAN   

  • Published:1987-06-25

通过2-和4(或5)-咪唑基甲醛分别与吡咯缩合,合成了meso-四(2-咪唑基)卟啉和meso-四[4(或5)-咪唑基]卟啉,并考察了它们的水溶性质.最后用这种四咪唑基卟啉制备了10种金属卟啉配合物.

关键词: 卟吩 P, 咪唑 P, 咪唑 P, 缩合反应, 抗癌药, 催化剂, 助剂, 络合试剂, 水溶性, 金属络合物, 有机合成, 吡咯 P, 性质, 甲醛 P

Water-sol. meso-tetra(2-imidazolyl)porphyrin and meso-tetra(4(or 5)-imidazolyl)porphyrin were prepared by reaction of pyrrole with 2- or (4(or 5)-imidazolecarbaldehydes, resp., and characterized by electron absorption spectra, 1H NMR and elemental anal. Fe(III), Co(II), Ni(II), Cu(II) and Zn complexes of the porphyrins were prepared

Key words: PORPHINE P, IMIDAZOLE P, IMIDAZOLE P, CONDENSATION REACTION, ANTICARCINOGEN, CATALYST, ADDITIVES, COMPLEXIONS, WATER SOLUBILITY, METAL COMPLEX, ORGANIC SYNTHESIS, PYRROLE P, PROPERTIES, FORMALDEHYDE P

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