有机化学 ›› 2008, Vol. 28 ›› Issue (05): 768-774. 上一篇    下一篇

综述与进展

离子液体/超临界二氧化碳两相体系在有机合成中的应用

范晖华,王阿忠,杨少容,江焕峰*   

  1. (华南理工大学化学科学学院 广州 510640)
  • 收稿日期:2007-08-25 修回日期:2007-09-17 发布日期:2008-05-20
  • 通讯作者: 江焕峰

New Advances in Applications of Ionic Liquid/Supercritical Carbon Dioxide Biphasic Systems to Organic Synthesis

FAN Hui-Hua,WANG A-Zhong,YANG Shao-Rong,JIANG Huan-Feng*   

  1. (College of Chemistry, South China University of Technology, Guangzhou 510640)
  • Received:2007-08-25 Revised:2007-09-17 Published:2008-05-20
  • Contact: JIANG Huan-Feng

介绍了近年来在离子液体/超临界二氧化碳两相体系中进行有机合成的最新进展, 包括烯烃氢甲酰化反应、酶催化反应、二氧化碳和环氧化物的环加成反应、烯烃环氧化反应、烯烃不对称二羟化反应、氢化反应、Heck反应、醇氧化反应、烯烃氢乙烯化反应、烯烃二聚反应等.

关键词: 离子液体, 超临界二氧化碳, 两相体系, 反应

New advances in applications of ionic liquid/supercritical carbon dioxide biphasic systems to organic synthesis are reviewed. The reactions include hydroformylation of alkenes, enzyme-catalyzed transformations, cyclic-addition reaction of carbon dioxide to epoxide, epoxidation of olefins, asymmetric dihydroxylation of alkenes, hydrogenation reactions, Heck reaction, oxidation of alcohols, hydrovinylation of alkenes and dimerisation of alkenes.

Key words: supercritical carbon dioxide, biphasic system, reaction, ionic liquid