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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (02): 268-270. 上一篇    

研究简报

含席夫碱和酰胺单元的新型双杯[4]芳烃的合成

杨发福*,1,2，郑林禄1，季衍卿1，郭红玉1，林建荣1   

  1. 福建师范大学化学与材料学院 福州 350007)
    (2中国科学院福建物质结构研究所结构化学国家重点实验室 福州 350002)
  • 收稿日期:2005-01-17 修回日期:2005-09-02 发布日期:2006-01-21
  • 通讯作者: 杨发福

Synthesis of Novel Biscalix[4]arene Containing Schiff Base andAmide Units

YANG Fa-Fu*,1,2,ZHENG Lin-Lu1,JI Yan-Qing1,GUO Hong-Yu1,LIN Jian-Rong1   

  1. (1 College of Chemistry and Materials, Fujian Normal University, Fuzhou 350007)
    (2 State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter,
    Chinese Academy of Sciences, Fuzhou 350002)
  • Received:2005-01-17 Revised:2005-09-02 Published:2006-01-21
  • Contact: YANG Fa-Fu

PDF

1465

被引次数

59

对叔丁基杯[4]芳烃-1,3-二醛基衍生物2与对叔丁基杯[4]-1,3-二酰肼衍生物4在稀释条件下进行“1＋1”分子间缩合反应, 高产率地合成了含席夫碱和酰胺单元的新型双杯[4]芳烃衍生物5. 所有新化合物的结构经元素分析、质谱、核磁共振谱等表征证实, 杯[4]芳烃单元均为1,3-桥联且采取锥式构象.

关键词: 双杯[4]芳烃, 合成, 席夫碱, 酰胺

Reacting 1,3-bis[2-(p-formylphenoxy)ethyloxy]-p-tert-butylcalix[4]arene 2 with 1,3-di(hydra- zinocarbonylmethoxy)-p-tert-butylcalix[4]arene 4 by 1＋1 intermolecular condensation under diluted condition, a novel biscalix[4]arene derivative 5 containing Schiff base and amide units was prepared in high yield. The structures of all new compounds were characterized by elemental analyses, 1H NMR and ESI-MS spectra, which indicated that calix[4]arene units adopt 1,3-disubstituted pattern and cone conformation.

Key words: synthesis, Schiff base, amide, biscalix[4]arene