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有机化学
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有机化学 ›› 2000, Vol. 20 ›› Issue (1): 94-97. 上一篇    下一篇

研究论文

4,5-四硫富瓦烯-双(2,3,6,7-二苯基-氮杂环庚烷-1-氧化物)的合成

曾和平   

  1. 华南师范大学化学系.广州
  • 发布日期:2000-02-25

Synthesis of 4,5-tetrathiafulvalene - bis (2,3,6,7- diphenyl -N- hetero - cycloheptane-1- oxyl)

Zeng Heping   

  1. E China Normal Univ., Dept of Chem.Guangzhou
  • Published:2000-02-25

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495

被引次数

5

为了发展转变点温度(Tc)高的有机磁性分子，设计合成了4,5-四硫富瓦烯－双(2,3,6,7-二苯基-氮杂环庚烷-1-氧化物)。反应混合物均经硅胶柱和设备HPLC分离和纯化，产物的结构由MS、^1^HNMR、^1^3CNMR等确定。

关键词: 富瓦烯, 氮杂环化合物, 氧化物, 环庚烷P, 质谱法, 质子磁共振谱法, 碳13核磁共振谱法, 磁性, 有机锡化合物

To developing high -Tc organic magnets based on aryl - substituted tetrathiafulvalene (TTF) donors with a multidimensional network of heteroatomic interactions, we have designed and synthesized of 4,5- tetrathiafulvalene-bis(2,3,4,7- diphenyl -N- hetero - cycloheptane -1- oxyl). The reaction products were isolated by preparative HPLC and identified by mass spectrometry, ^1H NMR and ^1^3C NMR.

Key words: FULVALENE (=BICYCLOPENTADIENYLI-DENE), NITROGEN HETEROCYCLICS, OXIDE, CYCLOHEPTANE P, MASS SPECTROGRAPHY, PROTON MAGNETIC RESONANCE SPECTROMETRY, C13 NMR SPECTROMETRY, MAGNETISM, ORGANO TIN COMPOUNDS

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