SIOC English
有机化学
高级检索

有机化学 ›› 2006, Vol. 26 ›› Issue (01): 9-18. 上一篇    下一篇

综述与进展

亚甲胺叶立德参与的[3＋2]环加成反应的最新进展

王峰，白东鲁*   

  1. (中国科学院上海生命科学研究院 上海药物研究所 上海 201203)
  • 收稿日期:2005-01-14 修回日期:2005-05-11 发布日期:2005-12-31
  • 通讯作者: 白东鲁

Recent Progress in [3＋2] Cycloaddition Using Azomethine Ylide

WANG Feng, BAI Dong-Lu*   

  1. (Shanghai Institute of Materia Medica, Shanghai Institutes for Biological Sciences,
    Chinese Academy of Sciences, Shanghai 201203)
  • Received:2005-01-14 Revised:2005-05-11 Published:2005-12-31
  • Contact: BAI Dong-Lu

PDF

3643

综述了亚甲胺叶立德的制备、它参与的[3＋2]环加成反应的反应机理、反应选择性及在天然产物全合成中的应用等方面的最新进展.

关键词: 亚甲胺叶立德, [3＋2]环加成, 天然产物, 1,3-偶极子

The paper reviews the recent progress in [3＋2] cycloaddition using azomethine ylide, including preparation of ylide, mechanism and selectivity of reaction, and application in the total synthesis of natural products.

Key words: [3＋2] cycloaddition, 1,3-dipole, natural products, azomethine ylide