有机化学 ›› 2006, Vol. 26 ›› Issue (04): 497-503. 上一篇    下一篇

研究论文

新型三(四硫富瓦烯)环蕃的合成和性质

迟兴宝   

  1. (淮北煤炭师范学院化学系 淮北 235000)
  • 收稿日期:2005-04-14 修回日期:2005-10-31 发布日期:2006-03-31
  • 通讯作者: 迟兴宝

Synthesis and Properties of New Tri(tetrathiafulvaleneo)cyclophanes

CHI Xing-Bao   

  1. (Department of Chemistry, Huaibei Coal Teacher College, Huaibei 235000)
  • Received:2005-04-14 Revised:2005-10-31 Published:2006-03-31
  • Contact: CHI Xing-Bao

利用四(3'-碘丙硫基)四硫富瓦烯和四硫富瓦烯二钠盐反应合成新的三(四硫富瓦烯)环蕃, 并通过循环伏安法和化学氧化法分别对其氧化还原性质和紫外光谱进行了研究.

关键词: 四硫富瓦烯, 合成, 循环伏安, 紫外光谱, 环蕃

New tri(tetrathiafulvaleneo)cyclophanes were synthesized by treating tetrakis(3'-iodopropylthio)- tetrathiafulvalene with tetrathiafulvalene-dithiolate. Their electrochemical properties and UV spectra were studied by cyclic voltammetry and chemical oxidation, respectively.

Key words: cyclic voltammetry, synthesis, UV spectra, cyclophane, tetrathiafulvalene