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有机化学
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有机化学 ›› 2007, Vol. 27 ›› Issue (04): 532-535. 上一篇    下一篇

研究简报

三芳基膦配体的合成研究

郭妤，马梦林，彭宗海，郑学丽，陈华*，李贤均   

  1. (四川大学化学学院有机金属络合催化研究所 绿色化学与技术教育部重点实验室 成都 610064)
  • 收稿日期:2006-05-16 修回日期:1900-01-01 发布日期:2007-03-29
  • 通讯作者: 陈华

An Improved Synthesis of Triarylphosphines

GUO Yu, MA Meng-Lin, PENG Zong-Hai, ZHENG Xue-Li,
CHEN Hua*, LI Xian-Jun   

  1. (Key Laboratory of Green Chemistry and Technology, Ministry of Education, Institute of Homogeneous Catalysis,
    College of Chemistry, Sichuan University, Chengdu 610064)
  • Received:2006-05-16 Revised:1900-01-01 Published:2007-03-29
  • Contact: CHEN Hua

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被引次数

12 | 1

从间溴苯酚出发, 利用新的合成方法经五步反应合成了一系列具有不同烷氧基的芳基膦配体. 改进后的方法可方便地通用于在苯环上具有各种不同基团基的膦配体衍生物的合成, 且有原料易得、操作简单、产率较高的优点.

关键词: 合成, 三芳基膦, 单膦配体

A series of triarylphosphine ligands with alkoxyl groups have been prepared through five steps from commercially available 3-bromophenol by a new synthetic route. This improved synthetic procedure was straightforward, quick, reliable, and gave the triarylphosphine ligands with different substituents in good yields.

Key words: monophosphine, synthesis, triarylphosphine