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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (05): 599-609. 上一篇    下一篇

综述与进展

受限介质中光化学反应的研究

吕锋锋1，吴骊珠*,1，张丽萍1，佟振合*,1，郑利强2   

  1. (1中国科学院理化技术研究所 北京 100080)
    (2山东大学胶体与界面化学教育部重点实验室 济南 250100）
  • 收稿日期:2005-07-12 修回日期:2005-10-14 发布日期:2006-04-28
  • 通讯作者: 佟振合

Recent Advances of Photochemical Reactions within the Confined Media

LÜ Feng-Feng1,WU Li-Zhu*,1,ZHANG Li-Ping1,TUNG Chen-Ho*,1,ZHENG Li-Qiang2   

  1. (1 Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100101)
    (2 Key Laboratory of Colloid and Interface Chemistry, Shandong Unuversity, Ministry of Education, Jinan 250100)
  • Received:2005-07-12 Revised:2005-10-14 Published:2006-04-28
  • Contact: TUNG Chen-Ho

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1454

被引次数

18

提高化学反应的选择性始终是化学家关注的热点. 本工作以光Fries重排反应、Norrish/Yang光环化反应、9-取代蒽衍生物的光二聚反应以及不对称光化学反应为例, 结合近年来在受限介质中光化学反应研究的最新进展, 总结了利用受限介质控制化学反应选择性的一般规律.

关键词: 光反应, 选择性, 受限介质

The selectivity of the photochemical reactions is always an important concern of chemists. Herein the progress of photochemical reactions, including photo-fries rearrangements, Norrish/Yang photocyclization, dimerization of 9-substituted anthracenes and asymmetric photoreactions, within the confined media is reviewed and the general rules are summarized for microreactor-controlled selectivity of the photochemical transformations.

Key words: selectivity, photoreactions, confined media