有机化学 ›› 2005, Vol. 25 ›› Issue (06): 615-618.    下一篇

综述与进展

碘作为催化剂在有机合成中的应用

王宏社*,苗建英,赵立芳   

  1. (宝鸡文理学院化学化工系 宝鸡 721007)
  • 收稿日期:2004-05-17 修回日期:2004-11-05 发布日期:2005-05-30
  • 通讯作者: 王宏社

Application of Iodine as an Effective Catalyst to Organic Synthesis

WANG Hong-She*, MIAO Jian-Ying, ZHAO Li-Fang   

  1. (Department of Chemistry & Chemical Engineering, Baoji University of Arts and Sciences, Baoji 721007)
  • Received:2004-05-17 Revised:2004-11-05 Published:2005-05-30
  • Contact: WANG Hong-She

综述了单质碘作为催化剂在有机合成中的应用研究. 碘催化的反应主要涉及醚的去保护基, 酯化和酯交换反应、缩醛(酮)的形成、亲电取代反应、烯烃的氮杂环丙烷化、烯糖的糖苷化反应等.

关键词: 单质碘, 催化剂, 有机合成, 应用

The recent application of I2 as an effective catalyst to organic synthesis was reviewed, mainly focusing on reactions of selective deprotection of ethers, esterification and transesterification, acetalization and ketalization, electrophilic substitution and aziridination of olefins.

Key words: application, organic synthesis, iodine, catalyst