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有机化学
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有机化学 ›› 2006, Vol. 26 ›› Issue (06): 874-877. 上一篇    下一篇

研究简报

几个新型含氟化合物的合成

罗新湘*,1，黄筱玲2，曲凡歧2   

  1. (1湖南城市学院化学与环境工程系 益阳 413049)
    (2武汉大学化学与分子科学学院 武汉 430072)
  • 收稿日期:2005-12-22 修回日期:2006-04-22 发布日期:2006-05-31
  • 通讯作者: 罗新湘

Synthesis of Several Novel Fluorinated Compounds

LUO Xin-Xiang*,1,HUANG Xiao-Ling2,QU Fan-Qi2   

  1. (1 Department of Chemistry and Environmental Engineering, Hunan City University, Yiyang 413049)
    (2 College of Chemistry and Molecular Sciences, Wuhan University, Wuhan 430072)
  • Received:2005-12-22 Revised:2006-04-22 Published:2006-05-31
  • Contact: LUO Xin-Xiang

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被引次数

5 | 1

以3-硝基-4-氯三氟甲苯(1)为起始原料, 合成了新型含氟杂环化合物8和3个含氟中间体4, 5, 6. 通过IR, NMR, MS和元素分析对它们的结构进行了表征. 探讨了反应条件对产物结构的影响, 提出了化合物4可能的形成机理.

关键词: 3-硝基-4-氯三氟甲苯, 含氟化合物, 合成, 杂环

The synthesis of fluorinated heterocycle 8 and the three intermediates 4, 5 and 6 was first reported. The structures were determined by IR, NMR, MS spectra and elemental analysis. The influence of reaction conditions was explored and the possible mechanism of the formative of 4 was discussed.

Key words: fluorinated compound, heterocycle, synthesis, 3-nitro-4-chlorobenzotrifluoride